Synergistic interplay between photoisomerization and photoluminescence in a light-driven rotary molecular motor - Nature Communications

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Synergistic interplay between photoisomerization and photoluminescence in a light-driven rotary molecular motor - Nature Communications
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Fluorescence achieved in light-driven molecular motors univgroningen ScienceAdvances NatureComms

). The methyl groups at the pyrrole rings provide the perpendicular connection between the BODIPY plane and the naphthalene upper half of the MM with the dihedral angle of 87.6°. The ensuing spatial arrangement suppresses the direct π-system conjugation of the two functional moieties, still maintaining “moderate” interactions between the two moieties to obtain the synergistic effect.

). Finally, the PL intensity of the samples was recorded as a function of the wavelength and delay time, producing a PL map.

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